胆碱氨基酸离子液体改性生物质基碳量子 点复合润滑剂的制备及性能
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1.陕西科技大学;2.东南大学;3.浙江博菲电气股份有限公司

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TQ051

基金项目:

国家自然科学基金项目(面上项目,重点项目,重大项目);陕西省重点研发计划项目;陕西省教育厅科研计划项目


Preparation and properties of carbon quantum dot composite lubricant modified by biomas-based ionic liquid
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1.Shaanxi University of Science and Technology;2.Southeast University;3.Zhejiang Bofei Electric Co., LTD

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National Natural Science Foundation projects (surface projects, key projects, major projects); Key R&D project of Shaanxi Province; Scientific research project of Shaanxi Provincial Education Department

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    摘要:

    采用生物质材料制备了碳量子点(CQDs)和胆碱氨基酸离子液体(ILs),并通过ILs修饰CQDs获得CDILs复合润滑剂。采用FTIR、NMR、TEM对CDILs的结构和形貌进行了表征,并以摩擦系数和体积磨损率为考察指标,研究了CQDs和CDILs的添加量对其水基润滑剂摩擦学性能的影响,以及相关摩擦机理。结果表明:当CDILs添加量为0.3 wt%时,其水基复合润滑剂的摩擦系数和体积磨损率分别为0.14和1.91×10-9 mm3/(N·m),相比于纯水分别降低了33%和36%。在摩擦过程中,CDILs发挥了优异的协同作用,在金属摩擦表面形成连续、均匀、牢固的自润滑转移膜,防止了对磨表面的直接接触,使其复合润滑剂具有更加持久的减摩、耐磨性能。

    Abstract:

    Carbon quantum dots (CQDs) and choline amino acid ionic liquid (ILs) were prepared from biomass materials, and CDILs composite lubricant was obtained by modifying CQDs with ILs. The structure and morphology of CDILs were characterized by FTIR, NMR and TEM, and the effects of the addition of CQDs and CDILs on the tribological properties of water-based lubricants and the related friction mechanism were studied using the friction coefficient and volume wear rate as the indexes. The results show that the friction coefficient and volume wear rate of the water-based composite lubricant are 0.14 and 1.91×10-9 mm3/ (N·m), respectively, when the addition of CDILs is 0.3 wt%, which are 33% and 36% lower than that of pure water. In the friction process, CDILs plays an excellent synergistic role in forming a continuous, uniform and firm self-lubricating transfer film on the metal friction surface, preventing direct contact with the grinding surface, and making its composite lubricant have more lasting anti-friction and wear resistance.

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刘超,杨仓,唐雨凡,鲍艳,焦真,狄宁宇,陆云峰.胆碱氨基酸离子液体改性生物质基碳量子 点复合润滑剂的制备及性能[J].精细化工,2026,43(1):

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  • 收稿日期:2024-11-08
  • 最后修改日期:2024-12-30
  • 录用日期:2024-12-20
  • 在线发布日期: 2026-01-16
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