共轭微孔聚合物在光催化领域的应用进展
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1.沈阳化工大学 辽宁省特种功能材料合成与制备重点实验室;2.中国船舶重工集团有限公司第七二五研究所 海洋腐蚀与防护全国重点实验室;3.沈阳市新型功能涂层材料重点实验室;4.辽宁麦琪新材料集团有限公司

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辽宁省重点研发项目(2024JH2/102300004);辽宁省教育厅一般项目(LJ212410149032);辽宁省重点研发项目(2024JH2/102400048)。


Progress in the application of conjugated microporous polymers in photocatalysis
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1.Shenyang University of Chemical Technology, Liaoning Provincial Key Laboratory for Synthesis and Preparation of'' Special Functional Materials;2.State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute;3.Shenyang Key Laboratory for New Functional Coating Materials;4.Liaoning Maggie new Material Group Co., LTD

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Liaoning Province key research and development project(2024JH2/102300004);General Project of Education Dapartment of Liaoning Pronince(LJ212410149032);General Project of Education Dapartment of Liaoning Pronince(2024JH2/102400048)

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    摘要:

    共轭微孔聚合物(CMPs)是一类结合了π-π 共轭电子体系和微孔结构的先进有机多孔材料,近年来因其独特的物理化学性质被广泛应用于气体吸附、膜分离、催化、能源储存和阻燃等领域。自CMPs被报道以来,一直备受关注。因CMPs材料独特的孔道结构和表面性质,也越来越多地应用于光催化领域。本文首先简单介绍了CMPs的光催化机理;然后阐述了光催化性能提升方法,包括设计供体-受体(D-A)结构、引入杂原子,选择合适的单体、制备方法等,并总结了CMPs在光催化领域的应用,包括光催化产氢、光催化CO2还原、化合物合成;最后对CMPs的未来发展进行了展望,在持续提升CMPs光催化性能的同时,应更多考虑规模化生产中的技术路线设计问题,并将发展Schiff-base等非贵金属偶联反应,大比表面积与高导电性和机械强度有效平衡深入研究、微孔结构与性能构效关系理论模型构建、结合量子化学和人工智能等手段优化材料结构设计方法4个方面作为重点研发方向。 关键词:共轭微孔聚合物;光催化;光催化产氢;CO2还原;有机合成

    Abstract:

    Conjugated microporous polymers (CMPs) are an advanced organic porous material class combining π-π conjugated electronic systems with well-defined microporous structures. Owing to their unique physicochemical properties, CMPs have garnered significant attention in recent years and have been widely applied in gas adsorption, membrane separation, catalysis, energy storage, and flame retardancy. Since their initial discovery, CMPs have remained a focal point of research. Their distinctive pore structures and surface properties have made them increasingly attractive for photocatalytic applications. This review provides a concise overview of the photocatalytic mechanisms of CMPs, followed by a discussion of strategies to enhance their photocatalytic performance. These include the design of donor-acceptor (D-A) structures, heteroatom doping, selecting appropriate monomers, and optimizing synthetic methodologies. The applications of CMPs in photocatalysis are then summarized, focusing on photocatalytic hydrogen evolution, CO? reduction, and organic synthesis. Finally, future research directions are proposed. In addition to further improving the photocatalytic efficiency of CMPs, efforts should be directed toward addressing challenges in large-scale production, particularly in designing viable technological routes. Key areas of focus should include the development of Schiff-base and other non-noble metal coupling reactions, achieving a balanced integration of high surface area, electrical conductivity, and mechanical strength, constructing theoretical models to elucidate structure-property relationships in microporous materials, and leveraging quantum chemistry and artificial intelligence to optimize material design strategies. Key words: conjugated microporous polymers; photocatalysis; photocatalytic hydrogen production; CO2 reduction; organic synthesis

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林登杰,高慧颖,王娜,谢志鹏,刘国凯.共轭微孔聚合物在光催化领域的应用进展[J].精细化工,2026,43(2):

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  • 收稿日期:2025-02-19
  • 最后修改日期:2025-04-04
  • 录用日期:2025-03-17
  • 在线发布日期: 2026-02-12
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