明胶基耐水抗氧化薄膜的制备及性能研究
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江南大学 机械工程学院

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Preparation and properties of gelatin-based water-resistant antioxidant films
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Jiangnan University

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The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

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    摘要:

    以具有优异抗氧化能力的L-抗坏血酸(LA)和具有良好紫外线吸收能力的水杨酸(SA)为原料,采用酰氯法合成L-抗坏血酸-水杨酸酯(LOHB),使其具备两者各自的特性。LOHB在40ug/ml时,DPPH自由基清除率已达到90%,在0.5mg/ml时,已实现对UVB、UVC的吸收。将 LOHB 加入到明胶溶液中,流延制备出复合薄膜,其抗氧化和抗紫外线性能显著提高,DPPH自由基清除率为62%,以及达到对UVB、UVC的吸收。玉米醇溶蛋白、松香与复合薄膜进行层合,提高了单层薄膜的耐湿性,吸湿率从95%下降到40%。同时,所构建双层膜的性能进一步提升,自由基清除率可达90%以上以及在单层薄膜基础上,又实现对UVA的部分吸收,进一步扩大了薄膜潜在的应用范围。

    Abstract:

    L-ascorbic acid-salicylic acid ester (LOHB) was synthesized by the chloride method using L-ascorbic acid (LA) with excellent antioxidant ability and salicylic acid (SA) with good UV absorption ability as raw materials, which possesses the properties of each of the two. The DPPH radical scavenging rate of LOHB has reached 90% at 40ug/ml, and the absorption of UVB, UVC and UVB has been realized at 0.5mg/ml. UVB and UVC absorption. LOHB was added to gelatin solution, and the composite film was prepared by casting, and its antioxidant and UV resistance was significantly improved, and the DPPH radical scavenging rate was 62%, as well as the absorption of UVB and UVC had been achieved. Corn alcohol soluble protein and rosin were laminated with the composite film to improve the moisture resistance of the monolayer film, and the moisture absorption rate decreased from 95% to 40%. At the same time, the performance of the constructed bilayer film was further improved, with a free radical scavenging rate of more than 90% as well as partial absorption of UVA on top of the monolayer film, further expanding the potential application range of the film.

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唐亚丽,雷志颖,卢立新,丘晓琳,潘嘹.明胶基耐水抗氧化薄膜的制备及性能研究[J].精细化工,2026,43(2):

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  • 收稿日期:2025-02-25
  • 最后修改日期:2025-04-03
  • 录用日期:2025-03-24
  • 在线发布日期: 2026-02-12
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