溶剂蒸发法制备高效氯氟氰菊酯微胶囊及其性能表征
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Preparation and Characterization of Lambda-cyhalothrin Microcapsules by Solvent Evaporation Method
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    摘要:

    针对高效氯氟氰菊酯使用过程中对人体皮肤的刺激性以及对水生生物的高毒性,以乙基纤维素为壁材,二氯甲烷为溶剂,通过设计L9(34)正交试验,采用溶剂蒸发法制备高效氯氟氰菊酯微胶囊,同时对微胶囊的理化性质和缓释特性进行表征。根据微胶囊平均粒径和未包封率的综合评分确定最佳制备工艺为:25%二氯甲烷,0.75%乙基纤维素,2%乳化剂,剪切8 min。扫描电子显微镜观察发现,所制微胶囊具有粒径大小均匀,表面光滑等特性;红外光谱图表明,高效氯氟氰菊酯被乙基纤维素包埋;释放特性曲线也表明微胶囊具有较好的缓释性能。该工艺操作简单,制备周期短,成囊性好,可为农药微胶囊的制备提供有效途径。

    Abstract:

    In order to solve problems such as skin irritation to human body and high toxicity to aquatic organisms during the process of using, the lambda-cyhalothrin microcapsules were prepared by solvent evaporation method using ethyl cellulose as wall material and dichloromethane as solvent, and the physical and chemical properties and slow-release characteristics of the microcapsules were characterized. L9 (34) orthogonal experiment was designed, comprehensive score composed of average particle size and unencapsulation rate was adopted, to establish the optimum preparation conditions. They were as follows: 25% methylene chloride, 0.75% ethyl cellulose, 2% emulsifier, and shear for 8 min. The microcapsules had uniform particle size and smooth surface through observation by scanning electron microscopy; The infrared spectrogram showed that the lambda-cyhalothrin were encapsulated by ethyl cellulose; Release characteristic curve showed that microcapsule had good slow release performance. The process has the advantages of simple operation, short preparation period and excellent encapsulation, it can provide one effective way for the preparation of pesticide microcapsules.

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冯建国.溶剂蒸发法制备高效氯氟氰菊酯微胶囊及其性能表征[J].精细化工,2018,35(8):

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历史
  • 收稿日期:2017-07-20
  • 最后修改日期:2017-11-15
  • 录用日期:2017-11-22
  • 在线发布日期: 2018-07-10
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